How to use this calculator
List each gas with its amount and say whether the amounts are mole fractions, mass fractions, moles or masses. Fractions don’t have to add to exactly 1: they are normalized. Add the pressure and temperature for partial pressures, density and volume.
Formulas
Worked example
Çengel 13-4: 3 kg O₂, 5 kg N₂ and 12 kg CO₂ at 300 kPa and 27 °C
- Moles: 3/32 = 0.0938, 5/28 = 0.1786, 12/44 = 0.2727 kmol; total N = 0.545 kmol.
- M = m/N = 20/0.545 = 36.7 kg/kmol, so R = 8.314/36.7 = 0.2265 kJ/kg·K.
- Mole fractions 0.172, 0.328, 0.500; the CO₂ partial pressure is 0.500 × 300 = 150 kPa.
- V = mRT/P = 20 × 0.2265 × 300/300 = 4.53 m³.
Frequently asked questions
When do I use mole fractions and when mass fractions?
Pressures and volumes follow mole fractions (Dalton and Amagat). Mass-specific properties such as cp in kJ/kg·K are averaged with mass fractions.
Is the mixture’s k the average of the k values?
No. Average cp and cv on the same basis first, then take k = cp/cv.